This can be done without needing to open several programs.
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The electronegativity and so we take those four electrons, we divide them in half, so we give two electrons to one carbon and two electrons to the other carbon. Those electrons equally, because both of those carbons have the same value for So with four electrons, we're going to divide Have these four electrons, and now we're trying toĬompare the electronegativity of carbon, to carbon, and obviously, that's the same electronegativity. When we get to this double bond here between the two carbons, we Steal those electrons, and same thing over here, carbon's more electronegative, so carbon steals those electrons too. So we think aboutĮlectronegativity differences, and we know carbon is moreĮlectronegative than hydrogen, so carbon's going to So you put in our bonding electrons, and let's just pick one of the carbons to start off with, let's say we're talking about the carbon on the right. And let's verify that, let's put in our bonding electrons, and let's calculate the oxidation state of carbon by using our Should be minus four, because that total has to sum to zero, but this time we have two carbons, so minus four divided by two gives us minus two,Įach carbon should have an oxidation state of minus two. What's the oxidation state of carbon in this molecule? Well hydrogen should be plus one, and we have four of themįor a total of plus four. Let's move on to another molecule here, so C2H4, this is ethene, or ethylene. Let's count them up here, one, two, three, four, five, six, seven, eight, so four minus eight is equal to minus four, so we already knew that minus four was going So we can see thatĬarbon is now surrounded by eight electrons right, Carbon is more electronegative, so it takes those electrons, and all the way around. Carbon's going to hog thoseĮlectrons in this bond. More electronegative than hydrogen, so the two electrons in this bond here, carbon is going to take both of them, so So which is more electronegative? We know that carbon is The more electronegative atom is going to take all of the electrons in the bond, so we need to think about electronegativity differences, and we're comparing carbon to hydrogen. But now we need to thinkĪbout these covalent bonds as being ionic, and so We subtract the number of valence electrons in the bonded atom, or the number of valence electrons carbon has in our drawing. Next, we think about the oxidation state for carbon, and we start with a number of valence electrons in the free atom, or the number of valence electrons that carbon is supposed to have, and we know carbon is supposed to have four valence electrons, so from that number, So remember, when we're calculating the oxidation state using dot structures, we're thinking about bonding electrons, and we know that each bond consists of two electrons, so we need to put in the bonding electrons for all of our bonds. So let's go ahead and verify that with our dot structure. The sum has to be equal to zero, so we know that carbon's oxidation state must be minus four immediately, since we only have one carbon here. General chemistry approach where we know that hydrogen usually has an oxidation state of plus one, and we have four hydrogensįor a total of plus four. So let's start with methane, and let's find the oxidation state of carbon and methane. In earlier video, we've already seen the definition for oxidation state, and also how to calculate it. In this video, we're going to find the oxidation state of carbon in several different molecules. but if what you want is the most probable answer for most cases (say in school), you could rely on the factors i mentioned above (columns in periodic table, electronegativity, and octat rule) because the definition of "usual" itself is somehow arbitrary, and the situations one atom could be in a molecue varies so much (this video shows the examples for carbons clearly, and which is the most "usual" one? i'm not sure)ģ. actually there's no way to figure out "usual" oxidation state of an atom including that of oxygen as far as i knowĢ. thus by the formula, the oxidation state of oxygen in many cases = expected # of electrons - actual # of electrons = 6 - 8 = -2ġ. and it actually loves and steals them from whomever as much as possible (up to 8 in sum by octat rule)ģ. but in many cases, oxygen has stronger electronegativity (you can see this as a kind of the extend of loving and stealing electrons from others) than others bonded to it. oxygen has usually (or expectedly) 6 electrons around it by its place on the periodic table columns (say group-6)Ģ. 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The boy may also have depression, and I have a few examples of this. In the second dream, the sun is a smiley face even though downright gruesome things happen within this dream so just another factor of toxic positivity. This has to convey the meaning of: "Someone is gone, but it's okay because I have to be happy" and we have seen this theme everywhere in the game: The boy loses something important to him, but he has to stay happy no matter how shitty he feels about it. When you put around three of them into the pool while setting up one of the guillotines, and empty the pool, their heads explode due to being so upset, and the other ones just laugh at their death. Another thing representing toxic positivity is the part of the second dream where we get these entities with heart-shaped heads. We see smiley faces everywhere even though the situation of the boy is fairly traumatic, especially in the second part of Dream Two, he puts on a smiley face mask, as if he has to force a smile and say that everything will be fine and to just smile no matter how bad the situation is. This game also expresses toxic positivity. The giant, evil smiley face entity may as well represent his trauma altogether, seeing how it was the one who most likely corrupted the characters and pretty much everything in the game, and as someone who has severe anxiety myself, I can confirm that anxiety does change the way you see things in life. His eye colors also invert in the third dream, his eyes become black with white irises, which tells us that this memory affected him gravely as in the other two dreams, his eyes weren't inverted. In the third and last dream, also the most disturbing one, directly represents him losing his dog in the woods, and everything of the third dream is once again drawn in black and red with creepy imagery. Before the second dream, the boy loses his bunny teddy in the lake, and the rabbit taking the bunny when he is in the dream and going into the rabbit hole, it directly visualizes the lake, and the cannibalistic bigger rabbit that comes out is what the boy is afraid of. We as well see his anxiety through the other dreams. This definitely tells us this boy has anxiety. In this part, after putting the toys together, these jellyfish-things start playing some sort of gong/symbal which causes the boy to freak out when it does it over and over again. Take one particular part in the first dream. The boy throughout the whole game is constantly mumbling and whimpering as if he was anxious about something and all of his dreams/nightmares are related to events that caused this anxiety, like when we are shown a bully who took his ball, he associates toys with evil, as the toys in Dream One are all black and red and all creepy looking. Good luck humanity, you’re going to need it.It has to be some form of anxiety, most likely PTSD. Well… that is if you ignore the fact that an estimated 23 billion humans died during the course of the war, multiple colony planets were rendered completely uninhabitable, and nearly all of Earth’s military forces and fleets were wiped out. Seems like a good ol’ fashioned happy ending right? Halo 3: Humanity as we know it is basically over.īy the end of Halo 3, Master Chief has defeated the Covenant, the Flood, and prevented the destruction of the entire galaxy. Here are 8 of our favorite examples of that. Some games however, despite how happy their ending seemed, were actually hiding some pretty depressing stories. Because of that, for a long time, games tended to stay clear of overtly depressing endings, for fear of alienating players who were invested in seeing their characters win in the end. After all, you as the player are the protagonist, so it’s natural to want everything to go right for your character. Sad endings in games can be really tricky. You Have the Power…Know How To Use It, Inc. 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Donkey Kong has also appeared in the Game & Watch Gallery series, Super Smash Bros. Donkey Kong characters have appeared in various Mario games including Mario Party, Mario Kart, Mario Golf, Mario Tennis, Mario Strikers, Mario Hoops 3-on-3, and Mario Baseball. When it came time for the game Mario Kart 64, Donkey Kong was added at the last minute, and the game's popularity has put Donkey Kong characters in Mario spin-off games ever since. appeared in the game Super Mario Kart for SFC/SNES as one of Mario's biggest characters due to his involvement in the Arcade titles. Donkey Kong series which was a spiritual successor to the original classic arcade games.īefore Donkey Kong Country was released, Donkey Kong Jr. While Paon was creating their Donkey Kong games, Nintendo created the Mario vs. Paon then created DK: King of Swing on the Game Boy Advance, Donkey Kong Barrel Blast on the Nintendo Wii, and DK: Jungle Climber on the Nintendo DS, none did good sales-wise. Rare remade the Donkey Kong Country trilogy on the Game Boy Advance, which received good sales, as well as Diddy Kong Racing DS on the Nintendo DS which sold well. The game was also a flop, and thus the series was given to the Japanese company named Paon. Nintendo then created the next platformer by themselves, titled Donkey Kong Jungle Beat. Before the 3D adventure, however, Rare also created the game Diddy Kong Racing, which was very popular, and later spawned two new spin-off game series ( Banjo-Kazooie and Conker series).Īfter Microsoft Game Studios acquired Rare in 2002, Nintendo handed the franchise to Namco who created the Donkey Konga series, a rhythm game trilogy, however, Donkey Konga did not get the widespread support of Donkey Kong Country and thus the third game was never released outside Japan. After two sequels and the spiritual successor trilogy Donkey Kong Land on the Game Boy and Game Boy Color, respectively, the Donkey Kong Country franchise went three-dimensional with the game Donkey Kong 64. The game established Rareware as the Donkey Kong series new developers. Donkey Kong was then retired as a character until he was eventually brought back in the game Donkey Kong Country on the Super Family Computer/Super Nintendo Entertainment System.ĭonkey Kong Country became the second best selling SFC/SNES game because of its use of pre-rendered graphics and its fun platforming gameplay. The game was a smash hit, and it warranted two arcade sequels, and the eventual uprising of a Video Game Industry powerhouse, that to this day is one of the biggest gaming companies. It started out with the game Donkey Kong in the Arcade machines which introduced the world to Donkey Kong, Mario, and the platforming genre. Jumpman (at the bottom) climbing the level 25m in order to reach the Lady kidnapped by Donkey Kong Sr., as seen in the game Donkey Kong. 2.6 Other Nintendo's Franchises and Spinoffs.for the Game & Watch, released in early 1983. While Donkey Kong is sometimes seen as a Mario spinoff, it is the predecessor to the Mario franchise, whose first game was Mario Bros. The character Donkey Kong, his family of sentient primates and allies are the usual protagonists of the Donkey Kong franchise. Shigeru Miyamoto is credited as being the franchise's creator, although Rare notably revitalized Donkey Kong with the release of Donkey Kong Country in 1994. Its first installment is the Donkey Kong arcade game, released in July 9, 1981. Various (arcade machines, ROM cartridges, disks, digital media)ĭonkey Kong is a series of multiple games owned by Nintendo. Īrcade, Game & Watch, Family Computer/Nintendo Entertainment System, Game Boy, Super Family Computer/Super Nintendo Entertainment System, Nintendo 64, Game Boy Color, Game Boy Advance, Nintendo GameCube, Nintendo DS, Nintendo Wii, Nintendo 3DS, Nintendo Wii U, Nintendo Switch Rare, Ltd., Namco, Paon, Retro Studios, Monster Games Inc. Typical logo commonly used in game titles of the Donkey Kong series. For other uses, see Donkey Kong (disambiguation). Most often, the conversion is to JPEG, which offers lossy compression, or PNG, which offers lossless compression. To overcome this, PSD is often converted to a file format that can compress the data. A free alternative to Adobe products is the GNU Image Manipulation Program, otherwise known as GIMP.ĭue to the size of PSD files, they are not easy to transport, store, or share. How to open a PSD file?Īdobe Photoshop is the most common program to open a PSD file. Use any available tools if you want to edit and manipulate your PSD file. 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The cityscape in Metropolis reflects how society evolved from being based on agriculture to industrialization. It has been deemed as a “masterpiece” by the Library of Congress and is often cited as one of the first films to combine science fiction with modern city life. The film presents a dystopian vision of an industrial society set in 2026, with high-rise buildings dominated by advertising billboards that bear resemblance to New York’s Times Square. It was one of the most expensive films made in the silent era, and its production involved elaborate sets and innovative special effects. Metropolis is a 1927 German expressionist film directed by Fritz Lang. Let’s take a look at some of the best German expressionism films. It was at this time that many Germans were feeling intense anxiety, fear, and even anger about their country’s government. This style began in Germany, but it spread all over Europe as well as America during the Great Depression because many people felt lost or hopeless due to financial crisis so they looked for an outlet like expressionism, which made them feel more alive through distortion and experimentation with color. The main goal for these directors was to provoke strong feelings from viewers through images on screen or sounds coming out of the cinema’s loudspeakers. Including Alfred Hitchcock’s Blackmail (1929) or Orson Welles’ Citizen Kane (1941). This type of filmmaking has had an influence on Hollywood films to date with their use of shadows, stylized sets, and camerawork, expressionistic acting techniques, etc. The style could be seen as reflecting the feelings of anxiety caused by WWI or it could also represent the optimism of post-WWI society. German Expressionism had both positive and negative qualities. German Expressionism is a movement that began in the early 20th century and lasted until World War II. German Expressionism was often used as a means of social criticism or commentary on the emotional state of Germany at the time. German Expressionism in film is a movement that utilized distorted sets, strong contrasts of light and dark, expressionistic acting, and other devices to evoke moods through visuals. GERMAN EXPRESSIONISM What Is German Expressionism? These artists were inspired by German writers like Nietzsche and Schopenhauer who promoted humanism in opposition to what they saw as nihilistic trends in modern society. This art form emerged from a time when Germany was changing, and it served to capture the mood of then-modern German culture. They focused on those things which seemed most threatening to them: poverty, disease, insanity, war, and death. Their artwork showed deep feelings of anxiety, angst, and anger at the injustices they saw around them. The artists used their work as a means to convey their thoughts about society at the time. Pabst Among many other directors who worked in this style. It was created in the early 20th century, primarily by German filmmakers such as Fritz Lang, F. It is characterized by the use of twisted shapes, vivid colors, and jarring contrasts to create images with emotional intensity. German Expressionism was an artistic movement that began in earnest at the start of the 20th century. The end of the tool can be used to grip and bend wire which is handy for attaching wire onto the screw terminals of switches and outlets. The wire gauges are shown on the side of the tool so you know which slot to use for stripping insulation. Strip Off Wire Insulation without Nicking and Damaging the Electric Wire!Ī wire stripping tool used to safely strip electrical wires. Tests standard 3-wire outlets UL Listed Light indicates if wiring is incorrect, Very handy and easy to use. Lights indicate if wiring is correct and indicator light chart is included Provides 6 probable wiring conditions that are quick and easy to read for ultimate efficiency It detects probable improper wiring conditions in standard 110-125 VAC outlets This is great to troubleshoot a problem with outlet circuit wiring, is also used by most inspectors to test for power and check the polarity of circuit wiring. The Quickest Way to Check for Faulty Electrical Wiring! Simply insert the end of the tester into an outlet, lamp socket, or hold the end of the tester against the wire you wish to test. This is a testing tool that is a Non-contact tester that I use to easily Detect Voltage in Cables, Cords, Circuit Breakers, Lighting Fixtures, Switches, Outlets and Wires. The Safest Way to Test Electrical Devices and Identify Electric Wires!
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